Several small packs followed the Frenchman to form minor breakaways, but the GC contenders and Froome were not interested.
The gap to the leaders expanded to nine minutes as Froome tucked into the chasing group, conserving energy before the brutal climbing at the end of the day.
The peloton's pace was non-existent as they allowed the front riders a mammoth 15-minute lead with Quintana kicked to put pressure on the yellow jersey as he climbed with verve, but Team Sky were concentrated on Froome's overall tactics to maintain his position.
Meanwhile, the three riders at the front swapped the lead over the final five kilometres.
The 176-kilometre stage from Montpellier to Mont Ventoux produced action and drama, as high winds in the mountains on Bastille Day in France cut the race short.
Froome fell in the final seconds of the race, as a zealous crowd blocked the way, and the Brit ran up the hill on foot to the finish line before boarding a neutral bike to complete the race, with team cars chasing.
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